Quick answer
Traditionally, a special test engine (CFR engine) is used, comparing the diesel’s ignition to reference fuels. Other ASTM methods calculate an estimate using fuel properties (e.g., density, distillation).
Detailed answer
Measuring the cetane number involves both direct engine testing and more convenient calculated methods. The CFR (Cooperative Fuel Research) engine test is considered the gold standard: technicians run the fuel in a single-cylinder test engine under controlled conditions, adjusting compression and injection timing until the ignition performance matches that of reference fuels with known cetane numbers. This method is highly accurate, but it’s also time-consuming and costly. Labs that perform this test require skilled operators and precise instrumentation.
Because of the expense and complexity of the CFR test, many refineries and quality control labs also rely on calculated indexes, like the Cetane Index. These estimates use physical properties of the fuel—often density and distillation range—to predict cetane. ASTM D976 and ASTM D4737 are examples of standards that define how to calculate these indexes. While they don’t require an engine test, they might not perfectly capture the impact of additives or unusual feedstocks.
In practice, a company might do a direct CFR engine test on representative batches of diesel to confirm baseline quality. Then, they’ll run daily or hourly checks using the quicker calculated method to ensure the fuel stays within specifications. It’s a bit like checking one dish with a taste test (very hands-on) and then using a formula to gauge the quality of subsequent batches.
Why does this matter for you, the driver? If you’re in a region like the UK, fuels must meet standards such as EN 590, which dictate a minimum cetane number. Knowing that your diesel has been tested—either through direct engine methods or reliably correlated calculations—offers peace of mind that it won’t cause excessive knocking or emissions.
For those diving into the world of biodiesel or alternative fuels, these tests become even more important. The chemical composition might differ significantly from standard petroleum diesel, and the correlation formulas might not be as accurate if you have unusual compounds in your blend. In that case, going the extra mile with a CFR engine test can confirm whether you meet or exceed the necessary cetane requirements.
Regardless of how it’s measured, the cetane number is key to predicting how fuel will behave once it’s injected into a hot, compressed cylinder. A high number means quick ignition and less noise, a low number spells potential trouble. The fact that multiple methods exist allows producers to balance accuracy with practicality—ensuring that the fuel you pump into your tank is up to scratch without forcing every batch to undergo an expensive engine test.
This multi-tiered approach helps keep diesel uniform across different regions and suppliers, so you don’t end up with drastically varying quality every time you fill up. It’s all part of a broader system to ensure vehicles run well and comply with emission regulations. So whether you’re topping off your tank in a small town or a bustling city, you can be fairly confident in what you’re getting, thanks to the layered testing of cetane number.
At the end of the day, CFR engine tests remain the definitive measure—if you really need to know the precise ignition quality of a specific diesel, that’s the route you’d take. For general commercial purposes, though, the faster, calculation-based methods get the job done, especially when used in tandem with occasional engine tests for calibration. Either way, measuring cetane number is how the industry ensures your diesel meets the demands of modern engines with minimal fuss.