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Fuel Tech Experts FAQ » Cetane/2-EHN » What is 2-EHN?

What is 2-EHN?

Alex by Alex

Expert answer:

0

Quick Answer

2-EHN (2-ethylhexyl nitrate) is the most common cetane improver additive used in diesel fuel. It’s a synthetic organic nitrate compound that effectively increases cetane numbers by 2-8 points depending on concentration. 2-EHN is widely used in commercial fuel blending and aftermarket cetane boosters due to its proven effectiveness and compatibility.

Expanded Answer (Simplified)

2-EHN stands for 2-ethylhexyl nitrate, which is the gold standard chemical for improving diesel fuel ignition quality. Think of it as the most trusted and widely used ingredient in cetane boosters – it’s been proven effective and safe through decades of use in both commercial fuel production and aftermarket additives.

This chemical works by breaking down under the high pressure and temperature conditions in your engine cylinder, creating reactive particles that help the diesel fuel ignite more quickly and completely. It’s particularly effective because it’s stable during storage but becomes very reactive when needed during combustion.

You’ll find 2-EHN in most commercial cetane booster products, typically at concentrations of 15-25%. It’s the ingredient that fuel companies and additive manufacturers rely on because it has a long track record of safety and effectiveness. When you see a cetane booster that mentions 2-EHN as an ingredient, you know you’re getting a proven, industry-standard product.

Expanded Answer (Technical)

2-EHN (2-ethylhexyl nitrate) represents the industry standard cetane improver compound, characterized by its molecular formula C8H17NO3 and optimized performance characteristics for diesel fuel ignition enhancement across diverse engine applications and operating conditions.

Chemical Structure and Properties

2-EHN exhibits specific molecular characteristics that make it highly effective as a cetane improver while maintaining stability and compatibility with diesel fuel systems.

  • Molecular formula: C8H17NO3 with branched alkyl chain structure
  • Molecular weight: 175.23 g/mol providing optimal volatility characteristics
  • Boiling point: 205-210°C ensuring appropriate volatility for fuel applications
  • Thermal stability: Stable at storage temperatures, reactive under compression conditions

Mechanism of Action

2-EHN functions through thermal decomposition under compression ignition conditions, producing reactive nitrogen and oxygen species that accelerate fuel ignition and combustion processes.

  • Decomposition temperature: 400-500°C under typical compression conditions
  • Free radical generation: NO2 and alkoxy radicals promoting ignition
  • Chain reaction initiation: Catalytic effect on fuel oxidation processes
  • Cetane improvement: 2-8 point increase depending on concentration and base fuel

Commercial Applications

2-EHN serves as the primary cetane improver in both refinery fuel blending operations and aftermarket additive formulations due to its proven performance and regulatory acceptance.

  • Refinery blending: Direct addition to diesel fuel during production
  • Aftermarket products: Active ingredient in consumer cetane boosters
  • Concentration ranges: 0.1-0.5% in fuel, 15-25% in commercial products
  • Regulatory status: Approved for use in most global fuel specifications

Safety and Handling Characteristics

2-EHN requires appropriate safety measures for handling and storage due to its chemical properties, while maintaining excellent compatibility with fuel system materials and emission control devices.

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